The Fe-57 Mössbauer Effect in Ferrocyanide Derivatives
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چکیده
منابع مشابه
Mössbauer diffractometry on polycrystalline 57 Fe 3
A Mössbauer powder diffractometer was used to measure diffraction patterns from polycrystalline foils of Fe3Al. The intensities of Bragg diffractions were measured as a function of the energy of the incident photon. The bcc fundamental diffractions showed large changes in intensity as the incident energy was tuned through the nuclear resonances. These variations of diffraction intensity with in...
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T. A. Stephens and B. Fultz Division of Engineering and Applied Science, mail 138-78, California Institute of Technology, Pasadena, California 91125 (Received 5 March 1996) Mössbauer diffraction was used to measure different autocorrelation functions for 57Fe atoms in different chemical environments. The sample was polycrystalline Fe3Al with the ordered DO3 structure. Diffraction peaks from a f...
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Diffraction patterns were measured on a polycrystalline bcc Fe foil using a Mössbauer powder diffractometer with high sensitivity. Measurements with and without a magnetic field normal to the scattering plane showed large differences in the diffracted intensities of the different nuclear resonances. These magnetic effects on diffraction intensities were interpreted successfully with a single sc...
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We report the results of density functional theory (DFT) calculations of the (57)Fe Mössbauer isomer shifts (delta(Fe)) for a series of 24 inorganic, organometallic, and metalloprotein/metalloporphyrin model systems in S = 0, (1)/(2), 1, (3)/(2), 2, and (5)/(2) spin states. We find an excellent correlation between calculation and experiment over the entire 2.34 mm s(-1) range of isomer shifts: ...
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Z. Naturforsch. 42b, 573-578 (1987); eingegangen am 8. Januar 1987 Phosphinetetracarbonyliron, Phosphitetetracarbonyliron, IR Spectra, P NMR Spectra, Fe Mössbauer Spectra A series of trigonal bipyramidal Fe(CO)4L complexes has been prepared and characterized by infrared, Fe Mössbauer and P NMR spectroscopy. A linear correlation, with a negative slope, between the CO stretching frequencies and t...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1965
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.38.684